|If I understand this.|
You have two hard drives.
One is small and the other big.
You want to clone the small to the big one.
Make the big one bootable
Then format the small one.
If you download.....say maxblast
Set the new bigger hard drive as slave
Have maxblast clone C: to I: using the make bootable option.
Then set you bigger drive to master and your old master to slave. (swap them)
You can then go into my computer...right click on the I:drive
(I: was the old C:) and format it.