|Is your laptop set up already for printing to that printer?|
If yes, then just double click on the icon for the photo and Windows will open the picture in its photo viewer program. There are print and print options there (I have not had XP at home for quite a while so I do not remember all of the details, but the options are there).
If no, then you need to set it up for printing first so include details.
Is the printer attached to another computer?
If yes, is it shared?
Is the printer networked?
Do you have wireless or wired access to the network, printer, or computer the printer is connected?
You have to be a little bit crazy to keep you from going insane.