The multiplier is probably locked, so that's not an option.
All Bartons run at 1.65v, so there's your default voltage. I wouldn't overvolt too much...but you're safe at 1.70, 1.75, even 1.80v. It probably wouldn't hurt to raise your RAM voltage a bit...default is usually 2.5v...but you're safe at 2.6 or 2.7v. Take the time to test your RAM too.
http://www.memtest86.com
If you have the option to do so, lock the PCI/AGP at their defaults (33/66mhz), otherwise they'll overclock along with the FSB...at 187mhz, the PCI is running at 37.4mhz...that's about the safe max. Much higher than that & you can expect problems.
Your temps are great so you have nothing to worry about in that respect. Keep an eye on them though...
One other thing to check would be the PSU. This gets mentioned a lot, but check the amps on the +12v rail. The Athlon gets it's power entirely from the +12v & uses about 8-10 amps. The HDD, optical drive, fans also use the +12v, so you need 16-18 amps to have all the bases covered.